![](http://4.bp.blogspot.com/-eXm_PV73FTQ/T2trwUK9ojI/AAAAAAAABdM/YBFelQw5bk8/s400/color%2Btheory%2Bsynthesis%2B7.png)
Take a look at the complimentary colors combinations on the left. Did you happen to think of the Hulk, or Superman? Comics, being a printed medium, are designed in CMYK, on which that color wheel is based. It seems pretty clear, to me at least, that a number of famous super hero's costumes were designed with the use of the complimentary colors of printing. I imagine it would simplify your printing costs when most of your character stable was made of simple primary colors.
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